| 16/08/2019 | 21:00 | Athletic Club | 1 | 0 | FC Barcelona |
| 25/08/2019 | 21:00 | FC Barcelona | 5 | 2 | Real Betis Balompié |
| 31/08/2019 | 17:00 | CA Osasuna | 2 | 2 | FC Barcelona |
| 14/09/2019 | 21:00 | FC Barcelona | 5 | 2 | Valencia CF |
| 17/09/2019 | 21:00 | BV Borussia 09 Dortmund | 0 | 0 | FC Barcelona |
| 21/09/2019 | 21:00 | Granada CF | 2 | 0 | FC Barcelona |
| 24/09/2019 | 21:00 | FC Barcelona | 2 | 1 | Villarreal CF |
| 28/09/2019 | 16:00 | Getafe CF | 0 | 2 | FC Barcelona |
| 02/10/2019 | 21:00 | FC Barcelona | 2 | 1 | FC Internazionale Milano |
| 06/10/2019 | 21:00 | FC Barcelona | 4 | 0 | Sevilla FC |
| 19/10/2019 | 13:00 | SD Eibar | 0 | 3 | FC Barcelona |
| 23/10/2019 | 21:00 | SK Slavia Praha | 1 | 2 | FC Barcelona |
| 29/10/2019 | 22:15 | FC Barcelona | 5 | 1 | Real Valladolid CF |
| 02/11/2019 | 17:00 | Levante UD | 3 | 1 | FC Barcelona |
| 05/11/2019 | 19:55 | FC Barcelona | 0 | 0 | SK Slavia Praha |
| 09/11/2019 | 22:00 | FC Barcelona | 4 | 1 | RC Celta de Vigo |
| 23/11/2019 | 14:00 | CD Leganés | 1 | 2 | FC Barcelona |
| 27/11/2019 | 22:00 | FC Barcelona | 3 | 1 | BV Borussia 09 Dortmund |
| 01/12/2019 | 22:00 | Club Atlético de Madrid | 0 | 1 | FC Barcelona |
| 07/12/2019 | 22:00 | FC Barcelona | 5 | 2 | RCD Mallorca |
| 10/12/2019 | 22:00 | FC Internazionale Milano | 1 | 2 | FC Barcelona |
| 14/12/2019 | 17:00 | Real Sociedad de Fútbol | 2 | 2 | FC Barcelona |
| 18/12/2019 | 21:00 | FC Barcelona | 0 | 0 | Real Madrid CF |
| 21/12/2019 | 17:00 | FC Barcelona | 4 | 1 | Deportivo Alavés |
| 04/01/2020 | 22:00 | RCD Espanyol de Barcelona | 2 | 2 | FC Barcelona |
| 19/01/2020 | 22:00 | FC Barcelona | 1 | 0 | Granada CF |
| 25/01/2020 | 17:00 | Valencia CF | 2 | 0 | FC Barcelona |
| 02/02/2020 | 22:00 | FC Barcelona | 2 | 1 | Levante UD |
| 09/02/2020 | 22:00 | Real Betis Balompié | 2 | 3 | FC Barcelona |
| 15/02/2020 | 17:00 | FC Barcelona | 2 | 1 | Getafe CF |
| 22/02/2020 | 17:00 | FC Barcelona | SD Eibar | ||
| 25/02/2020 | 22:00 | SSC Napoli | FC Barcelona | ||
| 01/03/2020 | 22:00 | Real Madrid CF | FC Barcelona | ||
| 07/03/2020 | 19:30 | FC Barcelona | Real Sociedad de Fútbol | ||
| 15/03/2020 | 02:00 | RCD Mallorca | FC Barcelona | ||
| 18/03/2020 | 22:00 | FC Barcelona | SSC Napoli | ||
| 22/03/2020 | 02:00 | FC Barcelona | CD Leganés | ||
| 05/04/2020 | 02:00 | Sevilla FC | FC Barcelona | ||
| 12/04/2020 | 02:00 | FC Barcelona | Athletic Club | ||
| 22/04/2020 | 02:00 | RC Celta de Vigo | FC Barcelona | ||
| 26/04/2020 | 02:00 | FC Barcelona | Club Atlético de Madrid | ||
| 03/05/2020 | 02:00 | Villarreal CF | FC Barcelona | ||
| 10/05/2020 | 02:00 | FC Barcelona | RCD Espanyol de Barcelona | ||
| 13/05/2020 | 02:00 | Real Valladolid CF | FC Barcelona | ||
| 17/05/2020 | 02:00 | FC Barcelona | CA Osasuna | ||
| 24/05/2020 | 02:00 | Deportivo Alavés | FC Barcelona |